Sigma vs Pi Bonds: What's the Difference?
You've drawn double bonds as two lines and triple bonds as three — but are those lines all the same? They're not. A double bond is really two different kinds of bond stacked together, and knowing the difference explains everything from bond strength to why some molecules can't twist. The short answer: a sigma (σ) bond forms when two orbitals overlap end-to-end , concentrating the shared electrons directly along the line between the two nuclei. A pi (π) bond forms when two p orbitals overlap side-by-side , placing electron density above and below that line. Every single bond is one sigma bond; double and triple bonds add pi bonds on top. Quick comparison at a glance Feature Sigma (σ) bond Pi (π) bond Orbital overlap End-to-end (head-on) Side-by-side (parallel p orbitals) Where the electrons sit Directly between the nuclei Above and below the bond axis Relative strength Stronger (more overlap) Weaker (less overlap) Rotation around the bond Fr...