Polar vs Nonpolar Bonds: What's the Difference?
You know a covalent bond means two atoms share electrons — but do they share fairly? Sometimes one atom pulls harder, and that tug-of-war is the whole difference between a polar and a nonpolar bond. The short answer: a nonpolar bond shares its electrons roughly equally, so no end of the bond is more negative than the other. A polar bond shares them unequally — one atom pulls the electrons closer and gains a small negative charge (δ−), leaving the other slightly positive (δ+). What decides which you get is the electronegativity difference (ΔEN) between the two atoms. Quick comparison at a glance Feature Nonpolar bond Polar bond Electron sharing Equal (or nearly) Unequal Electronegativity difference (ΔEN) Small (about 0–0.4) Moderate (about 0.4–1.7) Partial charges None δ+ on one atom, δ− on the other Typical atoms Same element, or two similar nonmetals Two different nonmetals Dipole (an "arrow" of charge) No Yes Examples H₂, Cl₂, O₂,...