Hydrogen Bonds vs Van der Waals Forces: The Difference
Both hold molecules together from the outside, both are far weaker than a real bond — so why does one get a special name? Hydrogen bonds and van der Waals forces sit in the same family, but the gap in strength between them explains some of chemistry's biggest surprises, like why water boils at 100 °C when it "should" boil far colder. The short answer: van der Waals forces are the weak, general attractions between molecules — mainly London dispersion forces and dipole–dipole forces . A hydrogen bond is a much stronger, special attraction that forms only when hydrogen is bonded to nitrogen, oxygen, or fluorine and is drawn to a lone pair on an N, O, or F in another molecule. Both are intermolecular forces; the hydrogen bond is just the strongest of the group. Quick comparison at a glance Feature Van der Waals forces Hydrogen bonds What they include London dispersion + dipole–dipole A special, strong dipole–dipole case Where they occur Between all mo...