What Is Effective Nuclear Charge? Zeff Made Simple
All week we've been saying atoms "pull harder" as you move across a period — smaller radii, pricier ionizations, hungrier electron affinities. But sodium's nucleus has 11 protons and chlorine's 17, while both sit behind the same 10-electron core. Why should six extra protons change so much? Time to meet the number quietly running every periodic trend. The short answer: the effective nuclear charge (Z_eff) is the net positive charge an electron actually experiences after the inner electrons cancel out part of the nucleus's pull — a shielding effect. A quick estimate: Z_eff ≈ Z − S , the atomic number minus the number of core (shielding) electrons. The nucleus behind bodyguards A valence electron never feels the bare nucleus. Between it and those protons sit the core electrons — full inner shells of negative charge that repel the outer electron and partially cancel the attraction. Chemists call this shielding (or screening). So the outer electron exper...