What Is Collision Theory? Why Reactions Need a Bump
Every particle in a beaker of solution collides with its neighbours trillions of times a second. If every one of those collisions caused a reaction, everything would react instantly and chemistry would be over. It doesn't, and collision theory explains why. The short answer: collision theory says that for particles to react they must collide , and that a collision only works if it has (1) at least the activation energy and (2) the correct orientation . Collisions meeting both conditions are called successful or effective collisions, and they are a small minority. The two conditions Condition 1 — enough energy. Reactions have to break bonds before they can make new ones, and breaking bonds costs energy. The minimum a colliding pair must bring is the activation energy, Eₐ . Below that, the particles simply bounce apart unchanged, however many times they meet. Condition 2 — correct orientation. Molecules aren't featureless spheres. The reactive part has to be pointing the...