What Is a Polar Molecule? Shape, Dipoles, and Water
Here's a puzzle that catches almost everyone: water (H₂O) is polar, but carbon dioxide (CO₂) is not — even though both are built from polar bonds. The answer isn't in the bonds at all. It's in the shape. The short answer: a polar molecule is one with an overall (net) separation of charge — a slightly positive end and a slightly negative end. That happens when a molecule has polar bonds and a shape lopsided enough that those bond dipoles don't cancel out. If the shape is symmetric and the pulls cancel, the molecule is nonpolar even with polar bonds. What "polar molecule" actually means Every polar bond has a little arrow of charge called a dipole , pointing from the δ+ atom toward the δ− atom. A molecule can have several of these arrows at once. To find the molecule's overall polarity, you add the arrows up like tug-of-war teams pulling in different directions: If the arrows cancel (equal and opposite), there's no net pull → nonpolar molecu...